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Are single-crystal battery cathode materials safe?

We show that single-crystal cathode materials are resistant to fracture and provide remarkable performance and safety characteristics unmatched by the state-of-the-art polycrystalline counterparts. A new path toward designing better battery cathode materials is revealed.

Can single-crystal materials be used in all-solid-state batteries?

The review concludes by proposing various strategies to optimize single-crystal technologies, targeting the development of efficient nickel-rich single-crystal materials for use in all-solid-state batteries.

Do solid-state batteries need a single-crystal morphology?

Solid-state batteries with no liquid electrolyte have difficulty accessing the lithium in the interior of large polycrystals, and can thus benefit greatly from single-crystal morphology. Including these two, eight publications have compared both the capacity and rate capability of single crystals and polycrystals.

Are single-crystal cathodes better than single-crystal LCO?

Compaction densities as high as 3.8 and 3.9 g/cm 3 have been reported, comparable to single-crystal LCO [13, 14]. Ultimately, the performance and stability of single-crystal cathodes is best demonstrated experimentally; Fig. 3 a shows a nearly crack-free cathode with 97% capacity retention after more than 5,000 cycles .

Is electrochemical-shock resistant single-crystal NMC a better battery cathode material?

Electrochemical-shock resistant single-crystal NMC reveals an alternative path towards developing better battery cathode materials, beyond the traditional one built upon polycrystalline NMC.

Are single-crystal cathode particles cyclable?

Single-crystal cathode particles with low susceptibility to cracking have recently taken on intense interest due to their remarkable cyclability. Many different approaches to single-crystal synthesis have been explored, but there has been no systematic analysis of the different techniques to date.

A perspective on single-crystal layered oxide cathodes for …

A perspective on single-crystal layered oxide cathodes for lithium-ion batteries. ... but draws on some of the vast knowledge on crystal growth outside the battery field to explain …

High-Voltage "Single-Crystal" Cathode Materials for Lithium-Ion ...

To boost the use of electronic devices and driving mileage of electric vehicles, it is urgent to develop lithium-ion batteries (LIBs) with higher energy density and longer life. High …

Single-crystal high-nickel layered cathodes for lithium-ion …

In summary, thanks to the reduction of high-reactive specific surface area and …

Single-Crystal Nickel-Based Cathodes: Fundamentals and

A comprehensive understanding of the growing body of research related to single-crystal materials is imperative to improve the performance of cathodes in LIBs. This review highlights …

A perspective on single-crystal layered oxide cathodes for …

Single-crystal layered-oxide cathodes have demonstrated excellent cycling performance across a range of compositions, particle sizes, and testing conditions. This can …

Single Crystal Layered Oxide Cathodes: The …

The need for longer-lasting batteries is driving the development of single crystal (SC) layered oxide cathodes (NCMs). ... comes with degradation issues 17 and fire hazards 18 that require new battery designs to be adopted. …

Up to One Million Kilometers: Revolutionary Single-Crystal …

POSTECH researchers have advanced electric vehicle battery technology by developing a method to synthesize durable single-crystal cathode materials, extending battery …

Long-Lasting Single-Crystal Batteries

6 · The single-crystal battery lasted over 20,000 cycles before reaching the 80% capacity threshold, equivalent to driving 8 million kilometres. In comparison, traditional lithium-ion …

Challenges and approaches of single-crystal Ni-rich layered …

Moreover, the single-crystal particle size can also be controllably regulated by changing the calcination temperature in the molten-salt synthesis route, that high temperature …

Syntheses, challenges and modifications of single-crystal cathodes …

On the other hand, in the PCC-containing battery, the electrolytes form a new solid–liquid interface through cracks, ... Li et al. [40] found that the dispersion and size of …

High‐Voltage Stability of Small‐Size Single Crystal Ni‐Rich …

In this work, small-size single crystal NCM811 (S-SC) is synthesized for sulfide-based ASSLBs to solve mechanical damage and contact failure issues. In addition, the …

Single crystal cathodes enabling high-performance all-solid-state ...

Single-crystal Li(Ni 0 · 5 Mn 0 · 3 Co 0.2)O 2 (SC-NMC532) was compared with their polycrystalline counterparts (PC-NMC532) in sulfide-based all-solid-state batteries. It is …

Single-crystal nickel-rich layered-oxide battery cathode materials ...

Electrochemical-shock resistant single-crystal NMC reveals an alternative path towards developing better battery cathode materials, beyond the traditional one built upon …

High‐Voltage Stability of Small‐Size Single Crystal Ni‐Rich Layered ...

In this work, small-size single crystal NCM811 (S-SC) is synthesized for …

Single Crystal Layered Oxide Cathodes: The Relationship between ...

The need for longer-lasting batteries is driving the development of single crystal (SC) layered oxide cathodes (NCMs). This work provides the conceptual framework for the …

Quantification of single crystallinity in single crystal …

Ni-rich single crystal cathodes (SCCs) are promising candidates for next-generation lithium-ion battery cathode materials. Their micron-sized particles, resembling single crystals, offer potential solutions to structural …

Single-Crystal Nickel-Based Cathodes: Fundamentals and

of the particle size and distribution, structural defects, and impurities to fully reap the benets of single-crystal materials. Keywords Lithium-ion battery · Cathode materials · Single crystal · …

Challenges and approaches of single-crystal Ni-rich layered …

Li et al. prepared a series of single-crystal cathodes by optimizing Li/TM ratio and calcination temperature, and found that the fastest crystallite growth condition is 970°C …

Single-Crystal Nickel-Based Cathodes: Fundamentals and

A comprehensive understanding of the growing body of research related to single-crystal …

Long-Lasting Single-Crystal Batteries

6 · The single-crystal battery lasted over 20,000 cycles before reaching the 80% …

A perspective on single-crystal layered oxide cathodes for lithium …

Single-crystal layered-oxide cathodes have demonstrated excellent cycling …

Challenges and approaches of single-crystal Ni-rich layered …

Li et al. prepared a series of single-crystal cathodes by optimizing Li/TM ratio …

Prospects and Strategies for Single‐Crystal NCM Materials to Solve …

This review aims to provide a comprehensive analysis of both the advantages …