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A schematic of a vanadium flow battery is depicted in Figure 1, in which two external tanks are used to carry vanadium ions in their various oxidation states (V 2+, V 3+, VO 2+, and VO 2+) with one redox pair present in each tank.
Thermal modeling of industrial-scale vanadium redox flow batteries in high-current operations A three-dimensional model for thermal analysis in a vanadium flow battery Vanadium redox battery: positive half-cell electrolyte studies Solubility of vanadyl sulfate in concentrated sulfuric acid solutions
In addition, the maximum system efficiency increased as the temperature increased. Moreover, the optimal flow factor at 10 °C and over 20 °C was one and two for the VFBs, respectively. Such an in-depth investigation is of solid significance for vanadium flow batteries to optimize their flow rate.
Authors to whom correspondence should be addressed. These authors contributed equally to this work. The vanadium flow batteries that employ the vanadium element as active couples for both half-cells, thus avoiding cross-contamination, are promising large-scale energy storage devices.
A three-dimensional model for thermal analysis in a vanadium flow battery Vanadium redox battery: positive half-cell electrolyte studies Solubility of vanadyl sulfate in concentrated sulfuric acid solutions The effect of additives on the low-temperature stability of the vanadium redox flow battery negative half-cell electrolytes
All vanadium RFB principles The all Vanadium Redox Flow Battery (VRB), was developed in the 1980s by the group of Skyllas-Kazacos at the University of New South Wales , , , .
Stabilizing multiple vanadium oxidation states in aqueous solution is a primary challenge in designing reliable large-scale vanadium redox flow batteries (VRBs). Here we demonstrate that rationally selected ionic …
Recent literature on the performance of vanadium redox flow batteries at low temperature shows degraded electrochemical performance attributable to increased …
The low temperature performance of rechargeable batteries, however, are far from satisfactory for practical applications. Serious problems generally occur, including decreasing reversible …
Among many energy storage technologies, the vanadium redox flow battery (VRFB) has high safety, long cycle life, good charging and discharging performance, rapid …
It shows that the temperature effect on the concentration polarization of reactive substances and the ionic mobility of H+ in the membrane may be the main factor affecting the …
In this paper, we present a physics-based electrochemical model of a vanadium redox flow battery that allows temperature-related corrections to be incorporated at a fundamental level, thereby extending its …
In this paper, we present a physics-based electrochemical model of a vanadium redox flow battery that allows temperature-related corrections to be incorporated at a …
This work presents a nonisothermal two-dimensional steady-state model of a unit-cell all-vanadium redox flow battery. The model is validated using polarization and open circuit voltage measurements at different …
Among various EESs, the all-vanadium redox flow battery (VRFB) is one of the most popular energy storage technology for grid-scale applications due to its attractive …
A comprehensive equivalent circuit model of all-vanadium redox flow battery for power system analysis. J. Power Sources 290, 14–24 (2015) Article Google Scholar Rao, …
In this work, the flow rate is optimized by incorporating the temperature effects, attempting to realize a more accurate flow control and subsequently enhance the performance …
Bismuth nanoparticle decorating graphite felt as a high-performance electrode for an all-vanadium redox flow battery. Nano Lett. 13, 1330–1335 (2013). Google Scholar Li, …
The ideal membrane should have high ion exchange selectivity, high ion conductivity, low water uptake, low swelling ratio, high conductivity, high chemical and thermal …
This work presents a nonisothermal two-dimensional steady-state model of a unit-cell all-vanadium redox flow battery. The model is validated using polarization and open …
As a large-scale energy storage battery, the all-vanadium redox flow battery (VRFB) holds great significance for green energy storage. The electrolyte, a crucial …
Vanadium/air single-flow battery is a new battery concept developed on the basis of all-vanadium flow battery and fuel cell technology [10]. The battery uses the negative electrode system of …
In this work, the flow rate is optimized by incorporating the temperature effects, attempting to realize a more accurate flow control and subsequently enhance the performance of vanadium flow batteries.
Trovò et al. [6] proposed a battery analytical dynamic heat transfer model based on the pump loss, electrolyte tank, and heat transfer from the battery to the environment. The …
The vanadium flow batteries that employ the vanadium element as active couples for both half-cells, thus avoiding cross-contamination, are promising large-scale energy …
The vanadium crossover through the membrane can have a significant impact on the capacity of the vanadium redox flow battery (VFB) over long-term charge–discharge …
Stabilizing multiple vanadium oxidation states in aqueous solution is a primary challenge in designing reliable large-scale vanadium redox flow batteries (VRBs). Here we …
As a large-scale energy storage battery, the all-vanadium redox flow battery (VRFB) holds great significance for green energy storage. The electrolyte, a crucial …
All-vanadium redox flow battery (VFB) is deemed as one of the most promising energy storage technologies with attracting advantages of long cycle, superior safety, rapid response and …
A parametric study on temperature distribution of vanadium redox flow battery was examined to understand thermal behavior at cold climate. Based on the results, an …
V anadium/air single-flow battery is a new battery concept developed on the basis of all-vanadium flow battery and fuel cell technology [10]. The battery uses the negative electrode system of the ...
It shows that the temperature effect on the concentration polarization of reactive substances and the ionic mobility of H+ in the membrane may be the main factor affecting the …