In this review, we introduce the recent research progress of proton batteries from three aspects and their integration: proton migration pathway (electrolyte), interfacial transport (electrolyte/electrode interface), and proton conduction mechanism (electrode structure).
Proton battery consists of electrolyte and corresponding proton storage host material (cathode/anode). Acidic electrolytes are usually considered as proton donors, such as H 2 SO 4, HCl, and H 3 PO 4, etc. It is worth noting that protons are often ignored in mild electrolytes.
As a matter of fact, the development of proton batteries can be traced back to lead-acid batteries, and proton storage is realized through chemical conversion . Then, nickel-metal hydride (Ni-MH) battery forms new compounds through redox reaction between host materials and protons.
Proton-conducting electrolytes is another area of the future development of proton batteries. Herein, the recent efforts of this emerging field of batteries are highlighted. The authors declare no conflict of interest. Proton, as a charge carrier, is most attractive due to its size and the associated advantages.
Proton batteries do not compete with nonaqueous batteries in energy density; the salient advantage of proton storage is its rate capability, which is associated with its tiny size and its nature of forming hydrogen bonding. The recent progress on Grotthuss proton storage is the high rate performance.
In short, proton battery works via the reversible insertion and deinsertion of protons in the host material to realize discharging and charging.
Download scientific diagram | Schematic illustration of the working principle of protic ionicliquid-based electrolytes in all-organic proton batteries. Reproduced from Ref. [55] with...
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Ascribed to their super-fast diffusion dynamics, proton batteries can afford both high energy density and high power density, which bridges the gap between lithium-ion batteries and …
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Download scientific diagram | Schematic illustration of the working principle of protic ionic‐liquid‐based electrolytes in all‐organic proton batteries. Reproduced from Ref. 55 with...
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Proton batteries do not compete with nonaqueous batteries in energy density; the salient advantage of proton storage is its rate capability, which is associated with its tiny size and its nature of forming hydrogen bonding. The …
Ascribed to their super-fast diffusion dynamics, proton batteries can afford both high energy density and high power density, which bridges the gap between lithium-ion …
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Proton batteries do not compete with nonaqueous batteries in energy density; the salient advantage of proton storage is its rate capability, which is associated with its tiny size …
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Download scientific diagram | Schematic illustration of the working principle of protic ionicliquid-based electrolytes in all-organic proton batteries. Reproduced from Ref. [55] with...
Figure 2 is the working principle diagram of the fuel cell. During the use of the fuel cell, electrons will accumulate on the battery surface and ions will accumulate on the electrolyte surface...
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In this case, two prominent scenarios are designed and proposed: the simultaneous power generation of wind turbine and proton-exchange membrane fuel cell (PEMFC) (first scenario) and fuel cell...
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